@article{3012703, title = "Phonon propagation in ordered diblock copolymer solutions", author = "Tommaseo, G. and Penciu, R.S. and Fytas, G. and Economou, E.N. and Hashimoto, T. and Hadjichristidis, N.", journal = "Macromolecules", year = "2004", volume = "37", number = "13", pages = "5006-5010", issn = "0024-9297, 1520-5835", doi = "10.1021/ma0496246", keywords = "Annealing; Block copolymers; Brillouin scattering; Dispersions; Elastic waves; Light scattering; Phonons; Rayleigh scattering; Refractive index; Solutions; Transmission electron microscopy; Vectors; X ray scattering, Elastic constants; Grain orientation; Microphase morphology; Sensitive index, Macromolecules", abstract = "High-resolution inelastic light scattering was employed to measure the dispersion relations for the acoustic excitations in ordered concentrated solutions of poly(styrene)-block-poly(isoprene) copolymers with both symmetric and asymmetric composition and large spacing (220-415 nm). The morphology is manifested in the rich phonon spectrum recorded for different scattering wave vectors q in the range 0.003-0.034 nm-1. The experimental ωa,(q) of the sth branch is directly compared with the theoretical dispersion from band structure calculations performed for different directions of q in the reciprocal lattice of lamellar and cylindrical periodic structures. The dispersion relations turn out to be a sensitive index of the microphase morphology and the grain orientation." }