@article{3059399, title = "Synthesis and spectroscopic characterization of new heteroleptic ruthenium(II) complexes incorporating 2-(2′-pyridyl) quinoxaline and 4-carboxy-2-(2′-pyridyl)quinoline", author = "Philippopoulos, A. and Falaras, P. and Chatzivasiloglou, E. and Igglessi-Markopoulou, O. and Likodimos, V. and Konti, G.-C.", journal = "Journal of Coordination Chemistry", year = "2012", volume = "65", number = "14", pages = "2535-2548", issn = "0095-8972, 1029-0389", doi = "10.1080/00958972.2012.698735", abstract = "Starting from cis-[Ru(dcbpyH 2) 2Cl 2] (1), two new heteroleptic ruthenium(II) complexes, [Ru(dcbpyH 2) 2(L 1)](NO 3) 2 (L 1=2- (2′-pyridyl)quinoxaline (2), and [Ru(dcbpyH 2) 2(L 2)](NO 3) 2 (L 2=4- carboxy-2-(2′-pyridyl)quinoline (4); dcbpyH 2=2,2′- bipyridine-4,4′-dicarboxylic acid), were synthesized and spectroscopically characterized. During the preparation of 2 and 4, the homoleptic [Ru(dcbpyH 2) 3]Cl 2 complex (3) was isolated as a side product. Characterization includes IR and Raman spectroscopy, UV-Vis, multinuclear NMR spectroscopy, elemental, and ESI-mass spectrometric analyses. © 2012 Taylor and Francis." }