@article{3072037, title = "Very large remanent polarization in ferroelectric Hf1-xZrxO2 grown on Ge substrates by plasma assisted atomic oxygen deposition", author = "Zacharaki, C. and Tsipas, P. and Chaitoglou, S. and Fragkos, S. and Axiotis, M. and Lagoyiannis, A. and Negrea, R. and Pintilie, L. and Dimoulas, A.", journal = "Applied Physics Letters", year = "2019", volume = "114", number = "11", publisher = "American Institute of Physics Inc.", issn = "0003-6951, 1077-3118", doi = "10.1063/1.5090036", keywords = "Deposition; Ferroelectricity; Germanium; Hafnium compounds; Oxygen; Polarization; Substrates; Zirconium compounds, Crystalline interfaces; Ferroelectric field effect transistors; Ferroelectric hysteresis; Germanium substrates; Metal-ferroelectric-semiconductors; Nonvolatile memory cells; Orthorhombic phase; Polycrystalline ferroelectrics, Field effect transistors", abstract = "Plasma assisted atomic oxygen deposition was used to grow polycrystalline ferroelectric Hf1-xZrxO2 (x = 0.5-0.7) on technologically important (100) Germanium substrates showing sharp crystalline interfaces free of interfacial amorphous layers and strong evidence for the presence of a predominately orthorhombic phase. The electrical properties, evaluated using metal-ferroelectric-semiconductor (MFS) capacitors, show symmetric and robust ferroelectric hysteresis with weak or no wake-up effects. The MFS capacitors with x = 0.58 show very large remanent polarization up to 34.4 μC/cm2 or 30.6 μC/cm2 after correction for leakage and parasitics, combined with good endurance reaching 105 cycles at a cycling field of 2.3 MV/cm. The results show good prospects for the fabrication of Ge ferroelectric field effect transistors (FeFETs) for use in 1 T FeFET embedded nonvolatile memory cells with improved endurance. © 2019 Author(s)." }