TY - JOUR
TI - Synthesis, Structure, and Antiproliferative Activity of Three Gallium(III) Azole Complexes
AU - Stergios Zanias
AU - Giannis S. Papaefstathiou
AU - Catherine P. Raptopoulou
AU - Konstantinos T. Papazisis
AU - Vasiliki Vala
AU - Dimitra Zambouli
AU - Alexandros H. Kortsaris
AU - Dimitrios A. Kyriakidis
AU - Theodoros F. Zafiropoulos
JO - Bioinorganic Chemistry and Applications
PY - 2010
VL - 2010
TODO - null
SP - 1--10
PB - Hindawi Limited
SN - 1565-3633, 1687-479X
TODO - 10.1155/2010/168030
TODO - null
TODO - As part of our interest into the bioinorganic chemistry of gallium,
gallium(III) complexes of the azole ligands 2,1,3-benzothiadiazole
(btd), 1,2,3-benzotriazole (btaH), and 1-methyl-4,5-diphenylimidazole
(L) have been isolated. Reaction of btaH or btd with GaBr3 or GaCl3
resulted in the mononuclear complexes [ GaBr3(btaH) 2] (1) and [
GaCl3(btd) 2] (2), respectively, while treatment of GaCl3 with L
resulted in the anionic complex (LH)(2)[GaCl4] (3). All three
complexes were characterized by single-crystal X-ray crystallography and
IR spectroscopy, while their antiproliferative activities were
investigated against a series of human and mouse cancer cell lines.
ER -