TY - JOUR
TI - Thermal Stability and Kinetics of Thermal Decomposition of Statistical Copolymers of N-Vinylpyrrolidone and Alkyl Methacrylates Synthesized via RAFT Polymerization
AU - Gikarakis, T.
AU - Pappas, I.
AU - Arvanitaki, P.
AU - Pantazi, E.
AU - Mitsoni, E.
AU - Roka, N.
AU - Pitsikalis, M.
JO - Internet Journal of Chemistry
PY - 2021
VL - 2021
TODO - null
SP - null
PB - Hindawi Limited
SN - 1099-8292
TODO - 10.1155/2021/6633052
TODO - null
TODO - The thermal stability and the kinetics of thermal decomposition of statistical copolymers of N-vinylpyrrolidone (NVP) with the alkyl methacrylates, hexyl methacrylate (HMA) and stearyl methacrylate (SMA), were studied by Thermogravimetric Analysis (TGA) and Differential Thermogravimetry (DTG). Statistical copolymers of different compositions were studied, and their thermal decomposition behavior was compared to the corresponding homopolymers. The activation energies of the thermal decomposition were calculated using the Ozawa-Flynn-Wall, the Kissinger, and the Kissinger-Akahira-Sunose methodologies. The effects of the nature of the methacrylate monomer, the copolymer composition, and the rate of heating are discussed. © 2021 Theodoros Gikarakis et al.
ER -