TY - JOUR TI - Resolution of 2, 3-Dideoxy-Dl-2-Enopyranos-4-Uloses via chromatographic separation of their diastereomeric O-Tert-Butyloxycarbonyl-L-Alanyl esters. A convenient synthesis of L- and D-Aculose 1. AU - Constantinou-Kokotou, V. AU - Couladouros, E.A. AU - Georgiadis, M.P. JO - Journal of Carbohydrate Chemistry PY - 1991 VL - 10 TODO - 5 SP - 749-756 PB - SN - 0732-8303, 1532-2327 TODO - 10.1080/07328309108543948 TODO - null TODO - A simple and effective procedure for the resolution of 2, 3-dideoxy-DL-2-enopyranos-4- uloses is presented. This procedure is based on column chromatographic separation of their diastereomeric 0-(N-rm-butyloxycarbonyl)-L-alanyl esters, followed by mild acidic cleavage of the ester function. L-Aculosc, 2, 3, 6-tridcoxy-L-glycero-hcx-2-cnopyranos-4-ulosc, is also prepared in satisfactory yield. © 1991, Taylor & Francis Group, LLC. All rights reserved. ER -