TY - JOUR
TI - Palladium catalyzed reductive decarboxylation of allyl α-alkenyl- β-ketoesters. A new synthesis of (E)-3-alkenones
AU - Ragoussis, V.
AU - Giannikopoulos, A.
JO - TETRAHEDRON LETTERS
PY - 2006
VL - 47
TODO - 5
SP - 683-687
PB - 
SN - 0040-4039
TODO - 10.1016/j.tetlet.2005.11.122
TODO - ester derivative;  formic acid derivative;  ketone derivative;  palladium;  palladium acetate;  tetrahydrofuran;  triethylammonium formate;  unclassified drug, article;  catalysis;  catalyst;  decarboxylation;  reduction;  stereochemistry;  synthesis
TODO - The reductive decarboxylation of α-alkenyl derivatives of allyl-β-ketoesters was achieved by use of palladium(0) catalyst generated in situ from Pd(OAc)2 and PPh3, with triethylammonium formate as the hydride source, in THF. The reaction proceeds smoothly and cleanly, with linear alkenyl derivatives of allyl-β-ketoesters, to afford (E)-3-alkenones in good to excellent yields (73-92%) and high stereoselectivity (>98%). © 2005 Elsevier Ltd. All rights reserved.
ER -