TY - JOUR
TI - A microporous Mg2+ MOF with cation exchange properties in a
single-crystal-to-single-crystal fashion
AU - Eleutheria Papazoi
AU - Antigoni Douvali
AU - Sofia Rapti
AU - Euaggelia Skliri
AU - Gerasimos S. Armatas
AU - Giannis S. Papaefstathiou
AU - Xin Wang
AU - Zhen-Feng Huang
AU - Spyridon Kaziannis
AU - Constantine Kosmidis
AU - Antonios G. Hatzidimitriou
AU - Theodore Lazarides
AU - Manolis J. Manos
JO - Inorganic Chemistry Frontiers
PY - 2017
VL - 4
TODO - 3
SP - 530--536
PB - Royal Society of Chemistry (RSC)
SN - 2052-1553
TODO - 10.1039/c6qi00548a
TODO - null
TODO - We report herein a new alkaline earth metal ion organic framework
[Mg-2(NH2BDC)(2)(HNO3)]center dot 9H(2)O (AEMOF-7), which shows a 3-D
microporous structure with several unusual features, such as the rare
trigonal prismatic coordination geometry of one of the
crystallographically unique Mg-2(+) centers and the existence of a
bridging HNO3 ligand. The H+ ions of the HNO3 ligand are dissociable as
demonstrated via proton conductivity measurements. AEMOF-7 displays
relatively high selectivity for CO2 vs. CH4 and negligible N-2 uptake.
Interestingly, this compound was found to be capable of
single-crystal-to-single-crystal (SCSC) exchange of Mg2+ by Cu2+ ions,
which was observed for the first time in a MOF material. AEMOF-7 is also
luminescent and its photophysical properties were investigated via solid
state UV-Vis, steady-state and time-resolved luminescence studies.
ER -