TY - JOUR
TI - Circular serendipity: in situ ligand transformation for the self-assembly of an hexadecametallic [CuII16] wheel
AU - Andreas K. Kostopoulos
AU - Athanassios D. Katsenis
AU - Jamie M. Frost
AU - Vadim G. Kessler
AU - Euan K. Brechin
AU - Giannis S. Papaefstathiou
JO - Chem. Commun.
PY - 2014
VL - 50
TODO - 95
SP - 15002--15005
PB - Royal Society of Chemistry (RSC)
SN - null
TODO - 10.1039/c4cc07582j
TODO - null
TODO - A [Cu-16(II)] wheel was isolated serendipitously from the reaction of
acetylacetone dioxime with copper(II) chloride and lanthanide ions in a
reaction initially designed to produce heterometallic 3d-4f cages. The
ligand has been transformed in situ to three different forms, all found
within the [Cu-16] wheel, with the original ligand completely absent.
ER -