@article{2928312, title = "A family of double-bowl pseudo metallocalix[6]arene discs", author = "Seán T. Meally and Cecelia McDonald and Georgios Karotsis and Giannis S. Papaefstathiou and Euan K. Brechin and Peter W. Dunne and Patrick McArdle and Nicholas P. Power and Leigh F. Jones", journal = "Dalton Transactions", year = "2010", volume = "39", number = "20", pages = "4809", publisher = "Royal Society of Chemistry (RSC)", issn = "1477-9226, 1364-5447", doi = "10.1039/b926704b", abstract = "We report the synthesis and magnetic characterisation of a series of planar [M-7] (M= Ni-II, Zn-II) disc complexes [Ni-7(OH)(6)(L-1)(6)](NO3)(2) (1), [Ni-7(OH)(6)(L-1)(6)](NO3)(2)center dot 2MeOH (2), [Ni-7(OH)(6)(L-1)(6)](NO3)(2)center dot 3MeNO(2) (3), [Ni-7(OH)(6)(L-2)(6)](NO3)(2)center dot 2MeCN (4), [Zn-7(OH)(6)(L-1)(6)](NO3)(2)center dot 2MeOH center dot H2O (5) and [Zn-7(OH)(6)(L-1)(6)](NO3)(2)center dot 3MeNO(2) (6) (where HL1 = 2-iminomethyl-6-methoxy- phenol, HL2 = 2-iminomethyl-4-bromo-6-methoxy-phenol). Each member exhibits a double-bowl pseudo metallocalix[6]arene topology whereby the individual [M-7] units form molecular host cavities which are able to accommodate various guest molecules (MeCN, MeNO2 and MeOH). Magnetic susceptibility measurements carried out on complexes 1 and 4 indicate weak exchange" }