TY - JOUR TI - 1D and 2D metal–organic frameworks functionalized with free pyridyl groups AU - Tamara D. Hamilton AU - Dejan-Krešimir Bučar AU - Manza B.J. Atkinson AU - Giannis S. Papaefstathiou AU - Leonard R. MacGillivray JO - Journal of Molecular Structure PY - 2006 VL - 796 TODO - 1-3 SP - 58--62 PB - ELSEVIER BV SN - 0022-2860 TODO - 10.1016/j.molstruc.2006.03.099 TODO - null TODO - We show that a molecule constructed from an organic solid-state synthesis, namely, rctt-1,3-bis(2-pyridyl)-2,4-bis(4-pyridyl)cyclobutane (ht-2,4 ‘-tpcb) upon reaction with Cu(II) and Zn(II) ions gives one- (1D) and two-dimensional (2D) metal-organic frameworks (MOFs) of composition [Cu(hfac)(2)(2,4 ‘-tpcb-ht)](infinity) (where: hfac=hexafluoroacetylacetonate) (1) and [Zn(2,4 ‘-tpcb-ht)(2)(H2O)(2)](infinity)(2+), (2). Each MOF possesses uncoordinated, or free, 2-pyridyl groups that decorate the walls of each extended structure. (c) 2006 Elsevier B.V. All rights reserved. ER -