@article{2928349, title = "Template-controlled reactivity: Following natures way to design and construct metal-organic polyhedra and polygons", author = "Tamara D. Hamilton and Giannis S. Papaefstathiou and Leonard R. MacGillivray", journal = "Journal of Solid State Chemistry", year = "2005", volume = "178", number = "8", pages = "2409--2413", publisher = "ELSEVIER BV", issn = "0022-4596, 1095-726X", doi = "10.1016/j.jssc.2005.05.034", abstract = "We show how a template-controlled reaction performed in the organic solid state can be used to construct a molecule that functions as an organic building unit of both a metal-organic polyhedron and polygon. The template is a small organic molecule that organizes two olefins via hydrogen bonds for a [2+2] photodimerization. The process of utilizing a molecule to build a molecule that is subsequently used for self-assembly is inspired by the general two-step process of template-directed synthesis and self-assembly of Nature that is used to construct large, functional self-assembled structures. (c) 2005 Elsevier Inc. All rights reserved." }