TY - CHAP
TI - Template-Controlled Synthesis in the Solid-State
AU - Leonard R. MacGillivray
AU - Giannis S. Papaefstathiou
AU - Tomislav Friščic
AU - Dushyant B. Varshney
AU - Tamara D. Hamilton
T2 - Templates in Chemistry I
PB - Springer Berlin Heidelberg
PY - 2005
SN - 978-3-540-44505-0
SP - 201--221
TODO - 10.1007/b99914
TODO - Linear templates, Photodimerization, Hydrogen-bonding, Preorganization, Molecular recognition, Self-assembly
TODO - The application of molecular templates to direct reactivity in the solid
state is described. Specifically, molecules that function as linear
templates are demonstrated to provide control of the [2+2]
photodimerization in the solid state such that it is possible to use the
templates to conduct target-oriented molecular syntheses, or molecular
syntheses by design. The degree of organization provided by the solid
state is also shown to provide chemists a reliable means to capture and
transform ordered complexes formed by way of hydrogen-bonded-driven
self-assembly into complex covalent molecular and polymeric structures.
ER -