@article{2928387,
    title = "An Inverted Metal-Organic Framework with Compartmentalized Cavities Constructed by Using an Organic Bridging Unit Derived from the Solid State",
    author = "Giannis S. Papaefstathiou and Leonard R. MacGillivray",
    journal = "Angewandte Chemie.  International Edition",
    year = "2002",
    volume = "41",
    number = "12",
    pages = "2070",
    publisher = "Wiley",
    issn = "1433-7851, 1521-3773",
    doi = "10.1002/1521-3773(20020617)41:12<2070::aid-anie2070>3.0.co;2-1",
    keywords = "metal-organic frameworks, solid-state, [2+2] photodimerization",
    abstract = "Gridlock: A porous metal–organic framework with an interior tailored supramolecularly with organic groups is described (see structure; two grids have been differentiated using cyan and gray, while the yellow spheres represent included methyl groups). The approach relies on inverting the role of a secondary building unit (SBU) and an organic linker such that the organic linker serves as a node and the SBU serves as a linear bridge. The organic node used to construct the framework has been obtained by way of a template‐directed solid‐state organic synthesis."
}