@article{2928390, title = "Discrete versus Infinite Molecular Self-Assembly:0.167em Control in Crystalline Hydrogen-Bonded Assemblies Based on Resorcinol", author = "Giannis S. Papaefstathiou and Leonard R. MacGillivray", journal = "Organic Letters", year = "2001", volume = "3", number = "24", pages = "3835--3838", publisher = "American Chemical Society (ACS)", issn = "1523-7060, 1523-7052", doi = "10.1021/ol0165948", abstract = "[GRAPHICS] Cocrystallization of 1,2-bis(4-pyridyl)ethane (4,4’-bipyeth) with resorcinol (res), 4-chlororesorcinol (4-Cl-res), and 4,6-dichlororesorcinol (4,6di-Cl-res) yields molecular solids (4,4’-bipyeth). (res) la, 2(4,4’-bipyeth).2(4-Cl-res) 1b, and 2(4,4’-bipyeth).2(4,6-di-Cl-res) is with components held together by 0-H . . .N hydrogen bonds. In 1a the components form an infinite 1D polar array, whereas in 1b and is the components form OD four-component complexes. Formation of the discrete assemblies is attributed to peripheral steric effects, which block the solid-state polymerization." }