TY - JOUR
TI - Alcoholysis of 2,2 ‘-pyridil, (2-C5H4N)C(O)C(O)(2-C5H4N), in the
presence of copper(II): A family of planar pentanuclear copper(II)
complexes stabilized by [(2-C5H4N)C(O)(OR)C(O)(OR)(2-C5H4N)](2-) and
carboxylate ligands
AU - Giannis S. Papaefstathiou
AU - Catherine P. Raptopoulou
AU - Alexandros Tsohos
AU - Aris Terzis
AU - Evangelos G. Bakalbassis
AU - Spyros P. Perlepes
JO - International Journal of Inorganic Chemistry
PY - 2000
VL - 39
TODO - 20
SP - 4658--4662
PB - American Chemical Society (ACS)
SN - null
TODO - 10.1021/ic991169k
TODO - polynuclear metal complexes
TODO - “Blends” of 2,2‘-pyridil, (2-C5H4N)C(O)C(O)(2-C5H4N), and carboxylate ligands, R‘CO2-, in alcohols (ROH) at room temperature are used to produce three clusters of the general formula [Cu5(OH)2{(2-C5H4N)C(O)(OR)C(O)(OR)(2-C5H4N)}2(O2CR‘)4(ROH)2]. The five CuII atoms are coplanar, exhibiting a rectangular arrangement of four metal ions with the fifth at the center of the rectangle. The representative complex with R = Et and R‘ = Me exhibits antiferromagnetic behavior.
ER -