TY - JOUR
TI - Bis[1,2-diphenyl-1,2-ethylenedithiolato(2-)-kS1,kS2] gold: Preparation, structure and properties
AU - George C. Papavassiliou
AU - George C. Anyfantis
AU - Catherine P. Raptopoulou
AU - Vassilis Psycharis
AU - Nikos Ioannidis
AU - Vassilis Petrouleas
AU - Patrina Paraskevopoulou
JO - Polyhedron
PY - 2009
VL - 28
TODO - 15
SP - 3368--3372
PB - ELSEVIER BV
SN - 0277-5387
TODO - 10.1016/j.poly.2009.05.045
TODO - Metal 1,2-dithiolenes; Crystal structure; Optical properties; EPR
spectra; Redox properties
TODO - Starting from 4,5-diphenyl-1,3-dithiol-2-one, the title complex was
prepared and studied. Single crystal X-ray structure determination
showed that the complex crystallized in the triclinic system, space
group P (1) over bar. It is isostructural with the beta-form of the
nickel analogue and the molecules have a dissymmetric structure.
Structural and EPR data were found to be close to the theoretically
calculated ones. Optical and electrochemical data indicate that the
complex is stable in air and could be a candidate material for
fabrication of electronic devices. (c) 2009 Elsevier Ltd. All rights
reserved.
ER -