@article{2959188, title = "Polymersomes with asymmetric membranes and self-assembled superstructures using pentablock quintopolymers resolved by electron tomography", author = "J. S. Haataja and N. Houbenov and V. Aseyev and P. Fragouli and H. Iatrou and R. Sougrat and N. Hadjichristidis and O. Ikkala", journal = "Chemical Communications (London)", year = "2018", volume = "54", number = "9", pages = "1085--1088", publisher = "Royal Society of Chemistry (RSC)", doi = "10.1039/c7cc07306b", keywords = "acetone; polymer; polystyrene block poly(1,4 isoprene)block poly(dimethylsiloxane)block poly(tert butylmethacrylate)block poly(2 vinylpyridine); unclassified drug, Article; chemical structure; electron tomography; polymerization", abstract = "Polystyrene-block-poly(1,4-isoprene)-block-poly(dimethyl siloxane)-block-poly(tert-butyl methacrylate)-block-poly(2-vinyl pyridine), PS-b-PI-b-PDMS-b-PtBMA-b-P2VP, self-assembles in acetone into polymersomes with asymmetric (directional) PI-b-PDMS membranes. The polymersomes, in turn, self-assemble into superstructures. Analogically to supravesicular structures at a smaller length scale, we refer to them as suprapolymersome structures. Electron tomograms are shown to be invaluable in the structural assessment of such complex self-assemblies. © 2018 The Royal Society of Chemistry." }