Unit:
Κατεύθυνση Οργανική ΧημείαLibrary of the School of Science
Author:
Τρούπα Παναγιώτα - ΝΙκολίνα
Supervisors info:
Σταματία Βασιλείου Λέκτορας (Επιβλέπουσα),Βικτωρία Μαγκριώτη Επίκ. Καθηγήτρια, Δημήτρης Γεωργιάδης Επίκ. Καθηγητής
Original Title:
Μικροκυματική υδροφωσφινυλίωση μη ενεργοποιημένων ακραίων αλκενίων χωρίς προσθήκη καταλύτη ή ριζικού εκκινητή
Translated title:
Microwave ydrofosfinyliosi unactivated alkenes extreme without adding catalyst or radical initiator
Summary:
In this thesis we studied the microwave-promoted phosphorus-carbon bond
formation between phosphinic acid/derivates and unactivated terminal alkenes
without added metal or radical initiator. At first, we search for the
appropriate conditions for the microwave-promoted hydrophosphinylation between
aqueous hypophosphorus acid and 1-decene. After finding the optimal conditions,
we isolated the products of hydrophosphinylation between aqueous hypophosphorus
and phenyl phosphinic acid with various unactived terminal alkenes as
substrates. Finally, the synthesis of phosphinic acid derivatives using
H-phosphinic acids as a source of P and unactived terminal alkenes was the last
stage of this work.
Keywords:
Organic Synthesis, Hydrophosphinylation, Microwave- promoted, Hypophosphorus acid, Terminal Alkenes
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