Unit:
Κατεύθυνση Ανόργανη Χημεία και ΤεχνολογίαLibrary of the School of Science
Author:
Παπαδοπούλου Έλλη
Supervisors info:
Ψαρουδάκης Νικόλαος Επίκ. Καθηγητής (Επιβλέπων), Κοΐνης Σπυρίδων Επίκ. Καθηγητής, Σημαντήρας Εμμανουήλ Β΄ Ερευνητής ΕΙΕ
Original Title:
Σύνθεση, μελέτη, χαρακτηρισμός και θεωρητικοί υπολογισμοί συμπλόκων ενώσεων των Zn2+, Cd2+ με την 2,3,9,10,16,17,23,24-τετράκις [(4,5-διμεθυλ-2,3-διιλδιθειο)-1,3-διθειολ] φθαλοκυανίνη
Translated title:
Synthesis, study, characterization and theoretical calculations of 2,3,9,10,16,17,23,24-tatra [(4,5-dimethyl-2,3-diildithio)-1,3-dithiole] phthalocyanine complexes with Zn2+, Cd2+
Summary:
In this thesis, a novel phthalocyanine and its complexes with Zn and Cd were
synthesized and characterized. The molecule of the synthesized compounds has,
per phthalocyanine unit, an additional ring with two sulfur atoms and two-SCH3
groups on that ring. The structures of these nοvel compounds were confirmed by
spectroscopic methods IR, Raman, 1H-NMR, UV-Vis, and TGA. Furthermore, the
conditions which promote aggregation were investigated via Uv-Vis electronic
spectroscopy. In addition, for the zinc metal complex the quantum yield was
calculated. Finally, theoretical calculations were also performed, using DFT,
and the results support the corresponding proposed structures.
Keywords:
Phthalocyanine, Aggregation, Fluorescence Quantum Yield, Spectroscopical Characterazation, DFT
