Unit:
Κατεύθυνση Ανόργανη Χημεία και ΤεχνολογίαLibrary of the School of Science
Author:
Ασημέλλης Ευστράτιος
Supervisors info:
Ψαρουδάκης Νικόλαος Επίκ. Καθηγητής (Επιβλέπων), Μεθενίτης Κωνσταντίνος Αναπλ. Καθηγητής, Σημαντήρας Εμμανουήλ Ερευνητής Β΄ Ε.Ι.Ε.
Original Title:
Σύνθεση,μελέτη και χαρακτηρισμός φθαλοκυανικών ενώσεων που παράγονται παρουσία Zn2+, Cd2+ όσο και απουσία αυτών στο 1,2-δικυανο 4,5-[(4,5-προπυλεν-2,3-διιλδίθειο)-1,3-διθειολ]βενζόλιο
Translated title:
Synthesis, study and characterization of phthalocyanine complexes, produced with or without the presence of Zn2+, Cd2+ with 1,2-dicyano-4,5-[(4,5-propylen-2,3-diildithio)-1,3-dithiole] benzene
Summary:
In this thesis one metal free and two new phthalocyanine complexes with Zn2+,
Cd2+ were synthesizedand characterized. These phthalocyanine complexes contain
two additional rings with four sulfur atoms per phthalocyanine substructure.
The synthetic route of the complexes appears diagrammatically in Scheme 1. The
synthesistook place in presence of appropriate metal salts(CdCl2
H2OorZn(CH3COO)2).The structures and synthesis of the new complexes were
confirmed by IR, Raman, UV-Visspectroscopy and TGA.Finally, theoretical
calculations were also performed to complexes and the results supported the
corresponding experimental data.
Keywords:
Phthalocyanine, Transition Metal Complexes, IR, Theoretical calculations, DFT
