Synthesis,characterization and study of catalytic activity of Ni(II) and Pd(II) complexes containing (P-N-P) type ligands

Postgraduate Thesis uoadl:1320169 285 Read counter

Unit:
Κατεύθυνση Ομογενής Κατάλυση
Library of the School of Science
Deposit date:
2016-10-20
Year:
2016
Author:
Κακρίδη Καλλιόπη
Supervisors info:
κ. Παναγιώτης Κυρίτσης Αναπλ. Καθηγητής
Original Title:
Σύνθεση,χαρακτηρισμός και μελέτη της καταλυτικής δραστικότητας συμπλόκων Ni(II) και Pd(II) με υποκαταστάτες τύπου P-N-P
Languages:
Greek
Translated title:
Synthesis,characterization and study of catalytic activity of Ni(II) and Pd(II) complexes containing (P-N-P) type ligands
Summary:
In this wok,the synthesis of bidentate ligands of the
phosporus-nitrogen-phosphorus type (P-N-P), along with the preparation of the
corresponding complexes of Ni(ΙΙ) and Pd(II) is described. The ligands and the
complexes were characterized using muclear magnetic resonance spectroscopies
(NMR), while the molecular structure in the crystal was analyzed by X-ray
crystallography studies.
The catalytic activity of the complexes was mainly studies in C-C bond
formation reactions. The Ni(II) and Pd(II) complexes were studied with respect
to their catalytic activity in Kumada and Stille reactions,respectively.
Keywords:
Aminobiphosphine ligands, Ni(II) and Pd(II) complexes, Catalytic cross-coupling reactions, Homogeneous catalysis
Index:
Yes
Number of index pages:
98-99
Contains images:
Yes
Number of references:
83
Number of pages:
108

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