Title:
A family of [Ni-8] cages templated by mu(6)-peroxide from dioxygen
activation
Languages of Item:
English
Abstract:
A family of exceptionally thermally stable [Ni-8] cages is reported,
each being templated by a rare eta(3):eta(3):mu(6)-O-2(2-) species
produced by dioxygen activation, where the reducing agent for the O-2
reduction appears to be the ligand used in the reaction mixtures, which
was found within the nickel cages in its oxidized form.
Authors:
Alexandros Perivolaris
Constantinos C. Stoumpos
Jolanta Karpinska
Alan G. Ryder
Jamie M. Frost
Kevin Mason
Alessandro Prescimone
Alexandra M. Z. Slawin
Vadim G. Kessler
Jennifer S. Mathieson
Leroy Cronin
Euan K. Brechin
Giannis S. Papaefstathiou
Journal:
Inorg. Chem. Front.
Publisher:
Royal Society of Chemistry (RSC)
Main subject category:
Science
Official URL (Publisher):
