Title:
An Inverted Metal-Organic Framework with Compartmentalized Cavities Constructed by Using an Organic Bridging Unit Derived from the Solid State
Languages of Item:
English
Abstract:
Gridlock: A porous metal–organic framework with an interior tailored supramolecularly with organic groups is described (see structure; two grids have been differentiated using cyan and gray, while the yellow spheres represent included methyl groups). The approach relies on inverting the role of a secondary building unit (SBU) and an organic linker such that the organic linker serves as a node and the SBU serves as a linear bridge. The organic node used to construct the framework has been obtained by way of a template‐directed solid‐state organic synthesis.
Authors:
Giannis S. Papaefstathiou
Leonard R. MacGillivray
Journal:
Angewandte Chemie. International Edition
Keywords:
metal-organic frameworks, solid-state, [2+2] photodimerization
Main subject category:
Science
Official URL (Publisher):
DOI:
10.1002/1521-3773(20020617)41:12<2070::aid-anie2070>3.0.co;2-1
