A Rod-Shaped Guest Leads to Architectural Isomerism in a Multicomponent Crystalline Framework Based on a Resorcin[4]arene

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Unit:
Department of Chemistry
Title:
A Rod-Shaped Guest Leads to Architectural Isomerism in a Multicomponent Crystalline Framework Based on a Resorcin[4]arene
Languages of Item:
English
Abstract:
Cocrystallization of C-methylcalix[4]resorcinarene 1 with
4,4’-bipyridine 2 in the presence of 4-bromobiphenyl (4-brbp) yields a
molecular solid, of composition 3d.(4-brbp), [where 3d = 1.2(2)], in
which 1 assembles with 2 to form a one-dimensional hydrogen-bonded
polymer 3d that includes two copies of the biphenyl, within elliptical
cavities of dimensions similar to11 x 7 x 6 Angstrom, as guests. The
framework 3d represents a third architectural isomer of three previously
reported supramolecular isomers of the parent material 3.
Publication year:
2001
Authors:
Leonard R. MacGillivray
Giannis S. Papaefstathiou
Jennifer L. Reid
John A. Ripmeester
Journal:
Crystal Growth & Design
Publisher:
American Chemical Society (ACS)
Volume:
1
Number:
5
Pages:
373--375
Main subject category:
Science
Official URL (Publisher):
DOI:
10.1021/cg0155245
The digital material of the item is not available.