Title:
Comparative study of the metal-ligand bond strength in Mn-II/X/U
complexes (X = Cl, Br, I; U = urea)
Languages of Item:
English
Abstract:
The synthesis, structure, vibrational analysis and a comparative
vibrational study in function of the structure and the metal-ligand bond
strength are discussed for a series of Mn(II)-urea-halogenide complexes.
Complex [MnCl2U] has been prepared and studied fur the first time. The
single-crystal X-ray structure of the 1:6-bromide complex reveals the
presence of octahedral [MnU6](2+) ions and bromide counterions. (C)
2000 Elsevier Science Ltd. All rights reserved.
Authors:
R Keuleers
G.S Papaefstathiou
C.P Raptopoulou
S.P Perlepes
H.O Desseyn
Journal:
Journal of Molecular Structure
Main subject category:
Science
Official URL (Publisher):
DOI:
10.1016/s0022-2860(00)00408-7
