5,10-dihydro-silanthrene as a reagent for the Barton-McCombie reaction

Scientific publication - Journal Article uoadl:2960841 6 Read counter

Unit:
Department of Chemistry
Title:
5,10-dihydro-silanthrene as a reagent for the Barton-McCombie reaction
Languages of Item:
English
Abstract:
The deoxygenation of secondary alcohols via thionoesters with the use of 5,10-dihydrosilanthrene as the radical reducing agent has been studied in detail. The ability of hydrogen donation of this silane has been measured using the one-carbon ring expansion of 1-(2-oxocyclopentyl)ethyl radical as a timing device.
Publication year:
1995
Authors:
T. Gimisis
M. Ballestri
C. Ferreri
C. Chatgilialoglu
R. Boukherroub
G. Manuel
Journal:
TETRAHEDRON LETTERS
Publisher:
ELSEVIER BV
Volume:
36
Number:
22
Pages:
3897--3900
Main subject category:
Science
DOI:
10.1016/0040-4039(95)00593-2
The digital material of the item is not available.