Κατεύθυνση Ανόργανη Χημεία και Εφαρμογές της στη Βιομηχανία
Library of the School of Science

2019-03-05

2019

Antonopoulou Aikaterini

Κυρίτσης Παναγιώτης, Αναπλ. Καθηγητής, Τμήμα Χημείας, ΕΚΠΑ
Δανόπουλος Ανδρέας, Καθηγητής, Τμήμα Χημείας, ΕΚΠΑ
Παπαευσταθίου Ιωάννης, Αναπλ. Καθηγητής, ΕΚΠΑ

Συσχέτιση δομικών και μαγνητικών ιδιοτήτων οκταεδρικών συμπλόκων Ni(II)

Greek

Magnetostructural correlations in octahedral complexes of Ni(II)

In the present work, reference is made to complex metal compounds of the first series of transition elements with behavior of mononuclear Single Molecule Magnets (SMMs). More emphasis is placed on the complexes of Ni(II), as the main part of work is concerned with the synthesis, characterization and study of the magnetic properties of a series of Ni(II) complexes with imidodiphosphinates and diimines as ligands.
A review of the complexes synthesized by employing the ligands Ph2P(O)ΝP(E)Ph2, Ε = Ο, S, Se, and the synthesis of six-coordinated complexes [Ni{Ph2P(O)NP(Ε)Ph2}(phen)(ΝΟ3)], Ε = Ο, S, Se, as well as of [Ni{Ph2P(O)NP(Se)Ph2}(phen)2]NO3 and [Ni{PhC(O)NP(O)Ph2}2(phen)] (phen = phenanthroline), is presented. An analysis of the IR and UV-Vis spectroscopic properties of the above complexes, as well as of their structural characteristics derived by X-ray crystallography, is also presented. Finally, the magnetic properties of these complexes, as derived by the application of appropriate magnetometry methods, are analyzed.

Science

nickel, imidodiphosphinato ligand, phenanthroline, single molecule magnets, magnetic properties.

Yes

1

Yes

70

108

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https://pergamos.lib.uoa.gr/uoa/dl/object/2864966