Di-2-pyridyl Ketone/Benzoate/Azide Combination as a Source of Copper(II) Clusters and Coordination Polymers: Dependence of the Product Identity on the Solvent

Scientific publication - Journal Article uoadl:2928329 134 Read counter

Unit:
Department of Chemistry
Title:
Di-2-pyridyl Ketone/Benzoate/Azide Combination as a Source of Copper(II) Clusters and Coordination Polymers: Dependence of the Product Identity on the Solvent
Languages of Item:
English
Abstract:
The reactions of di-2-pyridyl ketone with Cu(O2CPh)(2) in the presence
of NaN3 and LiOH have led to an antiferromagnetically coupled (S = 0)
Cu(II)6 cluster with a novel core and to (Cu-8(II))(n) and (Cu-2(II)),
coordination polymers (the former 1D and the latter 2D) with interesting
structures. The cluster or polymer formation depends on the reaction
solvent.
Publication year:
2008
Authors:
Theocharis C. Stamatatos
Vassilis Tangoulis
Catherine P. Raptopoulou
Aris Terzis
Giannis S. Papaefstathiou
Spyros P. Perlepes
Journal:
International Journal of Inorganic Chemistry
Publisher:
American Chemical Society (ACS)
Volume:
47
Number:
18
Pages:
7969--7971
Main subject category:
Science
Official URL (Publisher):
DOI:
10.1021/ic801196u
The digital material of the item is not available.