Κατεύθυνση Ανόργανη Χημεία και Εφαρμογές της στη Βιομηχανία
Library of the School of Science

2021-05-24

2021

Koutsouroumpi Christina

Μητσοπούλου Χριστίνα- Άννα, Καθηγήτρια, τμήμα Χημείας, ΕΚΠΑ

Σύνθεση και Χαρακτηρισμός Διθειολενικών Σύμπλοκων Νικέλιου(ΙΙ) και Εφαρμογή τους στη Φωτοκαταλυτική και Ηλεκτροκαταλυτική Παραγωγή Υδρογόνου

Greek

Synthesis And Characterisation of Dithiolene nickel (II) Complexes and their Application in Photocatalytic and Electrocatalytic Hydrogen Production

This work was conducted within the postgraduate thesis, at the Inorganic Laboratory of the Chemistry Department, UoA. The goal of this thesis is the study of systems for hydrogen production in homogeneous catalysis, as also the study of the systems using UV-Vis, IR and NMR spectroscopy and cyclic voltammetry. An effort was conducted to detect hydrogen in systems composed of fluorescein or [Ru(bpy)3Cl2] used as a photosensitizers (PS), nickel complexes as catalysts (Cat.), triethanolamine (TEOA) or a ascorbic acid/ sodium ascorbate buffer solution as electron donor (ED) and dimethylfurane (DMF) plus water (DMF:Η2Ο) as solvents. For hydrogen detection we used a gas chromatographer (GC) equipped with a thermal conductivity detector (TCD). Moreover, the complexes’ electrocatalytical hydrogen production was studied.

Science

Hydrogen, Dithiolene complexes, Nickel, Photocatalysis, Electrocatalysis

No

0

Yes

85

128

File access is restricted until 2024-05-25.

https://pergamos.lib.uoa.gr/uoa/dl/object/2946045