Title:
Self-Assembled Polymeric Supramolecular Frameworks
Languages of Item:
English
Abstract:
Within the framework: Ionic complexation of diblock copolypeptide poly(γ-benzyl-L-glutamate)-block-poly(L-lysine) (PBLG-b-PLL) with 2′-deoxyguanosine 5′-monophosphate (dGMP, gray) generates a polymeric supramolecular framework solid with self-assembled cages based on two orthogonal shape-persistent motifs: PBLG α helices (blue) and PLL β sheets (red), which in turn are held together by shape-persistent hydrogen-bonded G-ribbons. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Authors:
Nikolay Houbenov
Johannes S. Haataja
Hermis Iatrou
Nikos Hadjichristidis
Janne Ruokolainen
Charl F. J. Faul
Olli Ikkala
Journal:
Angewandte Chemie. International Edition
Keywords:
Diblocks; L-glutamate; l-Lysine; Monophosphates; Nano-materials; Self-assembled; Supramolecular framework, Amino acids; Macromolecules; Nanostructured materials; Nucleotides; Polymers; Porous materials; Self assembly, Supramolecular chemistry
Main subject category:
Science
Official URL (Publisher):
DOI:
10.1002/anie.201007185
