Novel Photocatalytic Organic Transformations for the Chemical Industry

Doctoral Dissertation uoadl:2963972 81 Read counter

Unit:
Department of Chemistry
Library of the School of Science
Deposit date:
2021-10-28
Year:
2021
Author:
Nikitas Nikolaos
Dissertation committee:
Χριστόφορος Κόκοτος, Αναπληρωτής Καθηγητής, Τμήμα Χημείας, ΕΚΠΑ
Δημήτριος Γεωργιάδης, Καθηγητής, Τμήμα Χημείας, ΕΚΠΑ
Γεώργιος Βουγιουκαλάκης, Αναπληρωτής Καθηγητής, Τμήμα Χημείας, ΕΚΠΑ
Βικτώρια Μαγκριώτη, Αναπληρώτρια Καθηγήτρια, Τμήμα Χημείας, ΕΚΠΑ
Αλέξανδρος Ζωγράφος, Αναπληρωτής Καθηγητής, Τμήμα Χημείας, Αριστοτέλειο Πανεπιστήμιο Θεσσαλονίκης
Μιχαήλ Σίσκος, Αναπληρωτής Καθηγητής, Τμήμα Χημείας, Πανεπιστήμιο Ιωαννίνων
Κωνσταντίνος Αθανασόπουλος, Αναπληρωτής Καθηγητής, Τμήμα Χημείας, Πανεπιστήμιο Πατρών
Original Title:
Καινοτόμοι Φωτοκαταλυτικοί Οργανικοί Μετασχηματισμοί για τη Χημική Βιομηχανία
Languages:
Greek
English
Translated title:
Novel Photocatalytic Organic Transformations for the Chemical Industry
Summary:
The application of Photochemistry in Organic Chemistry and especially in the field of catalysis has introduced new routes and reactivities, providing, in this way novel, green, and sustainable catalytic methodologies. The use of small organic molecules to promote photochemical transformations has been harnessed by researchers through the field of Photoorganocatalysis. In the first chapter of this thesis, an introduction on the activation modes and mechanisms in Photocatalysis is presented. In the second chapter, the most important photocatalysts are presented. The third chapter presents the goals of this thesis. The fourth chapter presents examples of photochemical reactions that are promoted by thioxanthone. The fifth chapter presents reactions that are promoted in the presence of various photoinitiators-photocatalysts, like activated carbonyl compounds or ruthenium complexes. The sixth chapter presents reactions that are promoted in the presence of phenylglyoxylic acid as the photoinitiator. Finally, the last chapter presents all experimental procedures and data.
Main subject category:
Science
Keywords:
Thioxanthone, Phenylglyoxylic Acid, Benzaldehyde, Acyl Chlorides, ATRA
Index:
No
Number of index pages:
0
Contains images:
No
Number of references:
160
Number of pages:
286
File:
File access is restricted until 2027-07-14.

Nikos_Nikitas_PhD.pdf
7 MB
File access is restricted until 2027-07-14.