Κατεύθυνση Ανόργανη Χημεία και Εφαρμογές της στη Βιομηχανία
Library of the School of Science

2024-06-27

2024

Gkeka Christina

Παναγιώτης Κυρίτσης, Καθηγητής, Τμήμα Χημείας, ΕΚΠΑ (Επιβλέπων).
Χριστιάνα Μητσοπούλου, Καθηγήτρια Τμήμα Χημείας ΕΚΠΑ,
Νίκος Ταγματάρχης, Διευθυντής Ερευνών ΕΙΕ

Ηλεκτροκαταλυτική παραγωγή υδρογόνου από σύμπλοκα [Co(II)S2Cl2], S = θειοσεμικαρβαζόνη, ελεύθερων ή ακινητοποιημένων σε MoS2

Greek

Electrocatalytic hydrogen production from [Co(II)S2Cl2] complexes, S = thiosemicarbazone, free or immobilized on MoS2

In the work described in this Thesis, the electrocatalytic evolution of hydrogen (HER) by two complexes of the Co(II)S2Cl2 type, S = thiosemicarbazone, is explored. The electrocatalytic activity of the two complexes is compared between each other, but also with that of literature Co(II) complexes with similar properties. The electrochemical data led to a series of additional experiments aiming at improving the lower HER activity of one of the two complexes. This endeavor took place via its immobilization on an appropriately modified MoS2 lattice. This system is also electrocatalytically active, opening up the prospect of its wider investigation, in an effort to design a high performance immobilized HER electrocatalyst.

Science

Co(II) complexes, Thiosemicarbazones, Electrocatalysis, Hydrogen Evolving Reaction, MoS2, Immobilization of catalyst

Yes

5

Yes

49

87

File access is restricted until 2027-06-27.

https://pergamos.lib.uoa.gr/uoa/dl/object/3402027