Κατεύθυνση Ομογενής Κατάλυση
Library of the School of Science

2011-12-05

2011

Κεφαλίδη Χριστίνα

Χ. Μητσοπούλου Καθηγήτρια Επιβλέπουσα

Φωτοκαταλυτική παραγωγή υδρογόνου με σύμπλοκα ρηνίου

Greek

This work was conducted within the graduate thesis in the field of Inorganic
Chemistry, University of Athens. It covers literature of photo-catalytic
systems for hydrogen production in homogeneous catalysis. We carried out
synthesis and characterization of the Re(CO)3Cl(bipy) and
Co(dmgH)2(-4-COOMe-py)Cl2 complexes using IR chromatography, UV-Vis, and NMR.
There’s been an attempt to detect hydrogen in the following systems:
Re(CO)3Cl(bipy)/Co(dmgH)2(-4-COOMe-py)Cl2/TEOA/HBF4,
Re(CO)3Cl(pq)/Co(dmgH)2(-4-COOMe-py)Cl2/TEOA/HBF4 and ReOCl3(pq)/
Co(dmgH)2(-4-COOMe-py)Cl2/TEOA/HBF4. The Re(CO)3Cl(bipy), Re(CO)3Cl(pq) and
ReOCl3(pq) complexes were used as photosensitizers (PS), the
Co(dmgH)2(-4-COOMe-py)Cl2 complex was used as electron donor (D) and TEOA as
electron relay (R), in DMF/H2O 3:5. For hydrogen detection we used gas
chromatographer TCB (Thermal Conductivity Detector).

Hydrogen production, Photosensitizer, Electron donor, Electron relay, Homogeneous Photocatalysis

Yes

8,9,10,11,66,67

Yes

83

80

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https://pergamos.lib.uoa.gr/uoa/dl/object/1320709