Τίτλος:
Synthesis and Characterisation of a Paramagnetic [2]Rotaxane Based on a Crown Ether-Like Wheel Incorporating a Nitroxide Motif
Γλώσσες Τεκμηρίου:
Αγγλικά
Περίληψη:
The synthesis of the new nitroxide crown ether 8 and its use as the wheel in a bistable [2]rotaxane, containing dialkylammonium and 4,4′-bipyridinium recognition sites, is reported. The synthesis of 8 was achieved by the sequential addition of substituted phenyl groups to a nitrone derivatives leading to the preferential formation of the cis stereoisomer. Due to charge–dipole interactions between the nitroxide unit and the bipyridinium moiety, it was possible to probe the movement of the macrocycle between the two molecular stations of the [2]rotaxane after addition of a base by measuring the nitrogen hyperfine splitting in the corresponding EPR spectra. The equilibrium constant for the complexation of dibenzyl viologen by the macrocycle 8 was also determined by EPR titration. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Συγγραφείς:
Bleve, V.
Franchi, P.
Konstanteli, E.
Gualandi, L.
Goldup, S.M.
Mezzina, E.
Lucarini, M.
Περιοδικό:
CHEMISTRY: A EUROPEAN JOURNAL
Εκδότης:
Wiley-VCH Verlag
Λέξεις-κλειδιά:
Electron spin resonance spectroscopy; Equilibrium constants; Ethers; Ligands; Molecular electronics; Supramolecular chemistry; Wheels, Charge-dipole interaction; EPR spectroscopy; Hyperfine splittings; Nitroxides; Recognition site; Rotaxanes; Sequential addition; Spin probe, Crown ethers
DOI:
10.1002/chem.201704969
