Τίτλος:
X-Ray Crystallographic Analysis, EPR Studies, and Computational Calculations of a Cu(II) Tetramic Acid Complex
Γλώσσες Τεκμηρίου:
Αγγλικά
Περίληψη:
In this work we present a structural and spectroscopic analysis of a copper(II) N-acetyl-5-arylidene tetramic acid by using both experimental and computational techniques. The crystal structure of the Cu(II) complex was determined by single crystal X-ray diffraction and shows that the copper ion lies on a centre of symmetry, with each ligand ion coordinated to two copper ions, forming a 2D sheet. Moreover, the EPR spectroscopic properties of the Cu(II) tetramic acid complex were also explored and discussed. Finally, a computational approach was performed in order to obtain a detailed and precise insight of product structures and properties. It is hoped that this study can enrich the field of functional supramolecular systems, giving place to the formation of coordination-driven self-assembly architectures. © 2017 Dimitrios Matiadis et al.
Συγγραφείς:
Matiadis, D.
Tsironis, D.
Stefanou, V.
Igglessi-Markopoulou, O.
McKee, V.
Sanakis, Y.
Lazarou, K.N.
Chrissanthopoulos, A.
Yannopoulos, S.N.
Markopoulos, J.M.
Περιοδικό:
Bioinorganic Chemistry and Applications
DOI:
10.1155/2017/7895023
