Τίτλος:
Circular serendipity: in situ ligand transformation for the self-assembly of an hexadecametallic [CuII16] wheel
Γλώσσες Τεκμηρίου:
Αγγλικά
Περίληψη:
A [Cu-16(II)] wheel was isolated serendipitously from the reaction of
acetylacetone dioxime with copper(II) chloride and lanthanide ions in a
reaction initially designed to produce heterometallic 3d-4f cages. The
ligand has been transformed in situ to three different forms, all found
within the [Cu-16] wheel, with the original ligand completely absent.
Συγγραφείς:
Andreas K. Kostopoulos
Athanassios D. Katsenis
Jamie M. Frost
Vadim G. Kessler
Euan K. Brechin
Giannis S. Papaefstathiou
Εκδότης:
Royal Society of Chemistry (RSC)
Κύρια θεματική κατηγορία:
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