Τίτλος:
Bis[1,2-diphenyl-1,2-ethylenedithiolato(2-)-kS1,kS2] gold: Preparation, structure and properties
Γλώσσες Τεκμηρίου:
Αγγλικά
Περίληψη:
Starting from 4,5-diphenyl-1,3-dithiol-2-one, the title complex was
prepared and studied. Single crystal X-ray structure determination
showed that the complex crystallized in the triclinic system, space
group P (1) over bar. It is isostructural with the beta-form of the
nickel analogue and the molecules have a dissymmetric structure.
Structural and EPR data were found to be close to the theoretically
calculated ones. Optical and electrochemical data indicate that the
complex is stable in air and could be a candidate material for
fabrication of electronic devices. (c) 2009 Elsevier Ltd. All rights
reserved.
Συγγραφείς:
George C. Papavassiliou
George C. Anyfantis
Catherine P. Raptopoulou
Vassilis Psycharis
Nikos Ioannidis
Vassilis Petrouleas
Patrina Paraskevopoulou
Λέξεις-κλειδιά:
Metal 1,2-dithiolenes; Crystal structure; Optical properties; EPR
spectra; Redox properties
Κύρια θεματική κατηγορία:
Θετικές Επιστήμες
DOI:
10.1016/j.poly.2009.05.045
